One such test that is most commonly used is known as the astm d976. Pdf evaluation of available correlations for prediction of diesel. Variations of cetane number of jatropha biodiesel blends. Neural network prediction of cetane number and density of diesel fuel from its chemical composition determined by lc and gcms article pdf. The equation for calculated cetane index in test method d976 80 and in this version d976 06 of the test method are the same.
The cetane index was calculated by astm d4737 and astm d976 and the derived cetane number dcn was measured using an ignition quality tester iqt. Two common tests are astm d976 and astm 4737 that use fuel density and boilingevaporation points to arrive at cetane ratings. Purchase your copy of astm d976 062016 as a pdf download or hard copy directly from the official bsi shop. Astm d976 062011 standard test method for calculated cetane index of distillate fuels. Pdf neural network prediction of cetane number and. Figure 2 shows the correlation between the measured cetane numbers and the cetane index as predicted using astm d976. Cetane index ci an approximation of cetane number based on an empirical relationship with density and volatility parameters. All bsi british standards available online in electronic and print formats. It plays a similar role for diesel as octane rating does for gasoline. Test method d is the preferred method as estimator of cetane number. This equation employs the same formulation as d97680 but differs from it, in that its middistillation. The present study is aimed at developing the mathematical relationship between viscosity, density, calorific value, flash point and cetane number cn.
Standard test method for cetane number of diesel fuel oil. Astm d7668 17 standard test method for determination of. It is a supplementary tool to estimate cetane number when used with due regard for its limitations. Astm d976 d4737 cetane index as a supplementary tool, the calculated cetane index by four variable equation must be used with due regard for its limitations. Cetane number is an important parameter in evaluating the quality of biodiesel fuel. In a particular diesel engine, higher cetane fuels will have shorter ignition delay periods than lower cetane fuels. Astm has recently released a new revision to standard test method for cetane number of diesel fuel oil, d617b, which incorporates changes that affects use of current diesel products by engine users. Generally, it has been found that use of test method d4737 results in less offset than use of test method d976, but there can be specific cases where this is not true. Referenced documents purchase separately the documents listed below are referenced within the subject standard but are not provided as part of the standard. Adjunct to d976 test methods for calculated cetane index of. No other units of measurement are included in this standard. This is an estimation of measured cetane number based on formulas in astm d976 or astm d4737. Cetane number cn a prime indicator of diesel fuel quality, is a quantity indicating the combustion behaviour of diesel fuel and compression required for ignition in diesel engines. Astm d976 062016 standard test method for calculated.
Research engine method astm d6 cetane number 2 and 4variable methods astm d976 and d4737 cetane index iqt method astm d6890 derived cetane number. Riazi10 was used to estimate the molecular weights of the diesel fuels. Cetane number determination of synthetic diesel fuels. This study examines the determination of cn of jatropha biodiesel blends with mineral diesel using their physical properties, and their variations of cn with. It is an unbranched alkane, a saturated hydrocarbon chain with no cycles. The cn is an important factor in determining the quality of diesel fuel, but not the only one. Astm d976062016 standard test method for calculated. Comparing methods to determine cetane ratings of fuel. Fast evaluation of cn supports efficient utilisation of the valuable cetane rich feedstock and helps to minimise giveaway. Figure 3 shows no 120 140 150 160 170 180 190 temperature figure i cetane number versus reaction temperatures at different space velocities. Test method d is the preferred method as estimator of cetane.
Limitations of the use of cetane index for alternative. Cetane number cetane rating is an indicator of the combustion speed of diesel fuel and compression needed for ignition. The calculated cetane index formula is particularly applicable to straightrun fuels, catalytically cracked stocks, and blends of the two. Astm d976 06 standard test method for calculated cetane. This interest covers both petroleumbased and syntheticbased, as well as blends thereof in order to i mprove the confidence in using dcn as a replacement test for cn. It is a supplementary tool asgm estimate cetane number when used with due regard for its limitations.
Product update for immediate release, july 2007 iqt. The sample population used to regress the formulas for d976 and d4737 are different, and the accuracy r, r is different. Astm d976 062016 standard test method for calculated cetane index of distillate fuels. It is a supplementary tool for predicting cetane number when used with due regard for its limitations. It is an inverse of the similar octane rating for gasoline petrol.
Method of compositional analysis of diesel fuels high performance liquid chromatographic. The calculations rely on diesel fuels t10, t50, t90 distillation points, and gravitydensity to estimate the cetane number. This method for estimating cetane number was developed by chevron research co. Astm d d pdf director august 31, 2019 admin personal growth leave a comment on astm d976 pdf. Astmd976 standard test method for calculated cetane. An equation was developed relating the cetane number and.
What effect does the cetane number have on engine performance. Standard test method for calculated cetane index of distillate fuels. Astm d976 pdf designation d 06 standard test method for calculated cetane index of free astm cetane number of distillate fuels from api gravity and. Astm d6890 is an approved alternative test method to d6 in us diesel spec astm d975. Test method d4737 procedure a may be less applicable to no. Note 1 this test method is temporarily retained because the proposal to the u.
In cases where the cetane number of a fuel has been initially established, the index is useful as a cetane number. Astm d976 062016 standard test method for calculated cetane. Pdf a database, containing some 76 diesel fractions from laboratory. Astm d976 d4737 cetane index this method for estimating cetane number was developed by chevron research co. Astm d976 062011 standard test method for calculated. The characterisation and cetane number determination of synthetic. Since using dedicated engines and processes or instruments for real fuel tests is painstaking, expensive, and timeconsuming, many diesel fuel formulators use a calculated method to determine cetane numbers. Cetane is the chemical compound with chemical formula nc 16 h 34, today named hexadecane according to iupac rules. Cetane number or cn is an indicator of the combustion speed of diesel fuel. Prediction of physical properties and cetane number of. It may be employed for approximating cetane number where the quantity of sample is too small for an engine rating. Its determination is usually arduous and expensive. Astm d976 04be1 standard test methods for calculated. In cases where the cetane number of a fuel has been initially established, the index is useful as a cetane number check on subsequent samples of that fuel, provided its source and mode of manufacture remain unchanged.
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